#6691. Charge transfer in photocatalysis of direct Z-scheme g-C3N4-based ferroelectric heterojunction

October 2026publication date
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Journal’s subject area:
Mechanical Engineering;
Metals and Alloys;
Mechanics of Materials;
Materials Chemistry;
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Abstract:
Great efforts have been made to enhance the photocatalytic efficiency of g-C3N4. The construction of Z-scheme g-C3N4-based ferroelectric heterostructures was considered to be an effective strategy to promote rapid carrier separation. However, the mechanism of charge transfer in the synergistic effect between Z-scheme g-C3N4-based heterojunction and ferroelectric polarization has not been thoroughly studied. Herein, g-C3N4-based ferroelectric catalysts with various bismuth ferrite (BiFeO3) contents have been prepared with a simple approach, and the direct Z-scheme heterojunction between BFO and g-C3N4 has been proved by experiments. Meanwhile, our study verified that the direct Z-scheme g-C3N4-based ferroelectric heterostructure plays a positive role in photocatalytic activity, and the charge transfer mechanism of this structure was discussed in detail, which provides a new strategy for improving the performance of g-C3N4-based ferroelectric catalysts.
Keywords:
BiFeO3/g-C3N4; Charge transfer mechanism; Ferroelectric; Photocatalytic; Z-scheme

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