#6473. Core-shell hetero-phase reduced Ti–Ni–O nanotubes photoanode with enhanced optical absorption and charge transport for boosted photoelectrochemical water splitting

November 2026publication date
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Journal’s subject area:
Condensed Matter Physics;
Energy Engineering and Power Technology;
Fuel Technology;
Renewable Energy, Sustainability and the Environment;
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Abstract:
Bulk-phase doping and surface oxygen-defective engineering of TiO2-based nanostructures are identified as effective routes for enhanced photoelectrochemical (PEC) water splitting. Here, we reported a reduced Ti–Ni–O nanotubes photoanode with anatase-rutile crystalline-core and oxygen vavancies amorphous-shell for boosted PEC water splitting. The core-shell hetero-phase reduced Ti–Ni–O nanotubes were fabricated through phase-structure modulation by a thermal treatment of anodized Ti–Ni–O nanotubes on Ti–Ni alloy and with one-step electrochemical reduction.
Keywords:
Anatase-rutile mixed-phase; Electrochemical reduction; Oxygen vacancies self-doping; Photoelectrochemical water splitting; Ti–Ni–O nanotubes

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