#6595. High-performance red and white organic light-emitting diodes based on a novel red thermally activated delayed fluorescence emitter in an exciplex matrix

December 2026publication date
Proposal available till 05-06-2025
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Journal’s subject area:
Nuclear Energy and Engineering;
Materials Science (miscellaneous);
Energy Engineering and Power Technology;
Fuel Technology;
Renewable Energy, Sustainability and the Environment;
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Abstract:
Blue and green organic emitters based on thermally activated delayed fluorescence (TADF) mechanism have made great progress in organic light-emitting diode (OLED) applications, whereas red and white OLEDs with this kind of emitters are lagging behind. In this text, we develop high-performance red and white OLEDs by doping a novel red TADF emitter 10,10-(11,12-diphenyldibenzo[a,c]phenazine-3,6-diyl)bis(10H-phenoxazine) (DBBPZ-DPXZ) into a blue emissive exciplex matrix. The highly rigid components and twisted donor-acceptor (D-A) structure of DBBPZ-DPXZ can suppress non-radiation decays and guarantee a small ?EST, which results in effective exciton utilization. Meanwhile, the exciplex matrix can also provide additional reverse intersystem crossing (RISC) channel and enhance the utilization of triplet excitons.
Keywords:
Blue exciplex host; Red emitter; Rigid components; Small singlet-triplet energy splitting

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